2016 Apr 27. doi: 10.1002/anie.201601834. [Epub ahead of print]
Abstract
The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)-catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
KEYWORDS:
cannabinoids; cycloisomerization; gold; oxy-Michael reaction; total synthesis
- PMID:
- 27119910
- [PubMed – as supplied by publisher]
